Attached to my reply is a snapshot of Excel 2010. Please confirm that you are talking about this feature of MS Excel. If yes then I am afraid, there is no functionality available in Aspose.Cells for .NET API to set the Gradient Fill Stop value other than 50%.
If you confirm this requirement, then we can log it as “Required Feature” in our system and support it in our future release.
I think you may use our latest version e.g v5.3.2, 5.3.3 to specify gradient stops. You cannot implement the advanced gradient options in older version like v4.4 that you are using. Please see the following sample code here.