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Thanks for your request. Yes of course you can do it using Aspose.Words. If you have lot of Word documents you can load each of them to documents and then concatenate these documents using AppendDocument method:
You can use Aspose.Words mail merge feature to fill your Word template with data. Please see the following link for more information.
And then convert this document to PDF:
Please let me know in case of any issues. I will be glad to help you.